Год выпуска: 2013 Автор: Sanjay Kumar Singh and Daya Shankar Pandey Издательство: LAP Lambert Academic Publishing Страниц: 180 ISBN: 9783659360381
Описание
Scientific community has shown decent research interest in the field of organometallic complexes based on platinum group metals owing to their plausible use in synthetic and industrial chemistry. In this regard, transition metal complexes containing ?6-arene, ?5-Cp and Cp* have drawn special attention. In particular, arene complexes have emerged as versatile intermediate in organic synthesis as a consequence of the ease with which the arene ligand can be functionalized. The presence of a transition metal center and ancillary ligands on one face of the coordinated arene can serve as a valuable stereochemical element. The utility of ?6-arene and ?5-Cp and Cp* metal complexes emanates not only from the reactivity inherent to the coordinated ring but, also from the control over three facially disposed coordinated sites about a given metal center afforded by incorporation of an arene ligand. In search of new systems based on arene ruthenium chemistry which can behave as potential...
