Год выпуска: 2012 Автор: Amjad Ali and Chebrolu Pulla Rao Издательство: LAP Lambert Academic Publishing Страниц: 220 ISBN: 9783846543689
Описание
The present book primarily deals with the lower rim substituted calix[4]arene derivatives and their metal ion complexes, and the biomimetic and biological studies of these complexes. Broadly, the book could be divided into the following three parts: (i) The K+ was found to act as template in the formation of calix[4]arene tetra-amide derivative exclusively, with the generation of calix[4]arene-monoanion and the structure of this has been characterized by single crystal XRD study. (ii) Metal ion complexes of p-tert-butylcalix[4]arene-diacid with Mn(II), Mn(IV), Fe(III), Co(II), Ni(II), Cu(II), Zn(II) and Sn(IV) have been discussed. Co-administration of lead and tin complexes on porphyrin metabolism, oxidative stress and distribution of metal ion concentration in blood and soft tissues in rats have been evaluated. (iii) Anthracene anchored derivatives of p-tert-butyl-calix[4]arene were subjected to the binding studies with the divalent metal ions. Based on the...