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Trimetallic Nitride Template Endohedral Fullerene Derivatives



Год выпуска: 2014
Автор: Julio R. Pinzon
Издательство: Scholars' Press
Страниц: 212
ISBN: 9783639719826
Описание
Among renewable energy sources, solar energy has the potential to meet the world's growing demand for energy in the future. Currently there are many research efforts to prepare materials for photovoltaics including organic molecules. Among them, fullerene derivatives have been identified as promising materials for the construction of plastic solar cells. In this work the preparation and electrochemical properties of donor–acceptor systems based on trimetallic nitride endohedral metallofullerenes (TNT-EMFs) for solar energy conversion is described. It was found that TNT-EMFs have an enhanced ability to stabilize charge separated states formed upon light irradiation when compared to empty cage fullerene analogues. Optimal conditions for preparing cyclopropanated Bingel-Hirsch derivaties of the most common TNT-EMFs were found. Novel D-A systems were prepared using this strategy and their electrochemical properties revealed that they form films by electro-oxidative polymerization. These...


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Александр
Марина, громко хлопаю в ладоши.Почему сразу нельзя было выслать такой вариант?Все равно огромное спасибо!